The industrial processes for recovery of niobium and tantalum oxides depend on hydrofluoric acid, which is a highly toxic and corrosive reagent with significant environmental consequences. This study presents a fluoride-free, rapid, and energy-efficient process for niobium and tantalum extraction from columbite using microwave-assisted …
The decrease of Nb/Ta in columbite– tantalite and of Zr/Hf in zircon is consistent with fractionation of a silicate melt (Linnen and Keppler, 1997, 2002). The most contentious question concerning the magmatic controls of mineralization is how the ore minerals, primarily columbite–tantalite, become saturated.
Columbite- (Fe) Wenger M, Armbruster T, Geiger C A (1991) Cation distribution in partially ordered columbite from the Kings Mountain pegmatite, North Carolina American Mineralogist 76 1897-1904. Columbite- (Fe) Tarantino S C, Zema M (2005) Mixing and ordering behavior in manganocolumbite-ferrocolumbite solid solution: A single-crystal X …
Zaraisky et al. (2010) determined the solubility of Ta 2 O 5 and Ta-bearing columbite in F− -, Cl − -, HCO 3− -, and CO 32 − -bearing solutions at 300–550 °C. The presence of F − increased the solubility of both phases by several orders of magnitude, indicating formation of F- or OH–F-bearing aqueous complexes.
tantalite ore prices had remained at $193 per kilogram of contained Ta 2 O 5 since november 2014. The increases in price in 2018 were thought to have resulted from a combination of increased demand from downstream consumers, increased royalties on exports of columbite-tantalite ore signed into law by the Government of Congo …
In this study, the columbite-tantalite group minerals (CGMs) from a typical Li-rich pegmatite dike were analyzed for major element contents using an EMPA (electron microprobe analyzer), for trace element contents using LA-ICP-MS (laser ablation-inductively coupled plasma mass spectrometry), and for ages using LA-ICP-MS U-Pb …
Abstract The paper presents experimental data on tantalite solubility in water-saturated granitoid melts with various alumina and alkaline elements concentrations at T = 650–850°C and P = 100 MPa. The maximum Ta concentration (effective solubility) in melt is shown to be always higher than the Nb concentration. As the melt composition is …
R41-1CH Columbite-Tantalite. 6.0 x 2.5 x 2.1 cm. This is a large, heavy, long prismatic, lustrous but opaque crystal cluster, combining two elements much in demand for making vital, metallic alloys. The color is blackish-brown, and the specimen is in very good shape, quite aesthetic overall. Ex.
Crystal System: Orthorhombic. Member of: Columbite Group > Columbite Supergroup. Name: From the manganese content and for the Greek mythical figure Tantalus - for its difficulty in dissolving. Type Locality: ⓘ Utö Mines, Utö, Haninge, Stockholm County, Sweden. Tantalite- (Fe)-Tantalite- (Mn) Series and Columbite- (Mn)-Tantalite- (Mn) …
It is chemically similar to Columbite, so you may also see it called columbite-tantalite in some places. It is also known by two other names depending on the exact makeup of the stones. The more common one is the manganese rich type which is called manganotantalite or less commonly, the iron rich variety called ferrotantalite.
Low solubility experimental data for columbite–tantalite in HCl, Na 2 CO 3, and NaHCO 3 solutions is important for understanding the genesis of hydrothermal Nb and Ta deposits. In HCl solutions, the Ta concentration ranges from 10 −7 to 10 −4 m under the P-T conditions of the experiments. In Na 2 CO 3 and NaHCO 3 solutions, the …
Coltan. Coltan is short for columbite-tantalite, a dull metallic ore. When refined, coltan becomes a heat resistant powder, metallic tantalum, which has unique properties for storing electrical charge. Coltan occurs in granitic pegmatites, pockets where the deep seated molten rock crystallized last. Pegmatites contain many rare metals, as well ...
The Chakabeishan (CKBS) deposit is the first pegmatite-type Li-Be deposit discovered in the eastern North Qaidam Tectonic Belt (NQTB) of Tibetan Plateau. The correct understanding of its petrogenesis and the precise determination of its formation age are of great significance for further regional prospecting and the discovery of new …
Jere et al. (1961) studied the thermodynamic basis of chlorination of oxides present in columbite-tantalite ore. Standard free energy and standard enthalpy change as a function of temperature was calculated. The results confirmed that Nb 2 O 5 had great tendency for chlorination at about 250 °C.
An assemblage of tantalite-(Mn), tantalian rutile, tapiolite-(Fe), titanowodginite, ferrotitanowodginite, and hydroxycalciomicrolite occurs in the Nancy granitic pegmatite, San Luis range, Argentina. The Nancy beryl-type, beryl–columbite–phosphate subtype of LCT (Li-Cs-Ta) rare-element pegmatite was emplaced in the Paleozoic Conlara pegmatitic …
Columbite-(Fe) is a post-magmatic accessory mineral occurring within syenogranites and greisens from the Desemborque Pluton. The petrographic (SEM) and geochemical (EPMA and LA-ICPMS) examination of this mineral shows two distinct textural types within both the rocks, named columbite-1 and columbite-2. The columbite-1 …
Tantalum and niobium are extracted from a variety of minerals and concentrates. The major source of niobium and tantalum is columbite-tantalite, also called coltan, with a general chemical formula (Fe,Mn)(Nb,Ta) 2 O 6.The two elements also exist in more than 150 other minerals and are usually present as complex metal oxides and …
In short, columbite-Fe is more common than columbite-Mn and in turn are both much more common than tantalite-Mn and the fourth example, tantalite-Fe, is actually very scarce. There are paragenetic guidelines. Associated iron and manganese bearing minerals tend to have a similar ratio of elements, but they need to be coeval.